Granule coated waterproof roofing membrane

ABSTRACT

A roofing membrane includes a membrane layer. An adhesive layer is adhered to a first side of the membrane layer and a layer of granules is adhered to the first adhesive layer.

RELATED APPLICATIONS

The present application is a divisional application of U.S. Ser. No.14/645,500, filed on Mar. 12, 2015, titled GRANULE COATED WATERPROOFROOFING MEMBRANE, which is a divisional application of U.S. Ser. No.13/614,001, filed Sep. 13, 2012, titled GRANULE COATED WATERPROOFROOFING MEMBRANE, now abandoned, which claims the benefit of U.S.provisional patent application No. 61/533,999, filed on Sep. 13, 2011,and titled “Roofing Membrane.” U.S. provisional patent application No.61/533,999 is incorporated herein by reference in its entirety.

FIELD OF THE INVENTION

Various embodiments of a granule coated waterproof roofing membrane aredescribed herein.

BACKGROUND OF THE INVENTION

A roof may have a steep-slope or a low-slope. Traditional tabbed orlaminated shingles are typically used for steep-slope roofingapplications. Traditional tabbed or laminated shingles are referred toas “water-shedding” products. That is, water that falls on a shingle onan upper portion of the roof runs down the shingle and onto anunderlying, next lower shingle. The water runs down the shingles, untilthe water reaches the bottom of the steep roof.

As the slope of a roof decreases, more emphasis is placed on the needfor waterproofing the roof covering, because less aid to physicalmovement of water is provided by the slope of the roof. Residential andcommercial products are available for low-slope roofing applications.Most products used in residential low-slope roofing applications includetwo or more plies or layers to enhance long-term performance. A typicallow-slope roofing product may have one or more underlayment or basesheets and a separate cap sheet. Typically, the separate cap sheets aresimilar to typical asphalt roofing shingles and may include a woven ornon-woven fiber mat that is coated on both upper and lower surfaces withasphalt. The separate cap sheet may have a layer of roofing granules onthe upper surface that is configured to match the roofing shingles of anearby steep-slope roof. One or both of the base sheet and the separatecap sheet may be self-adhering.

Many low-slope roofing products used in commercial applications arenon-asphalt based membranes that are installed on a low-slope roof usinga variety of attachment means, such as with cold or hot applied adhesivematerials, or with mechanical fasteners. The seams between portions ofthe membrane may be heat welded or glued. Typical commercial membranesare manufactured in solid colors, commonly white or black, and may belimestone covered. Other known low-slope roofing products includemembranes with patterns printed on the visible surface, and membranescoated with paint or a reflective coating.

SUMMARY OF THE INVENTION

The present application describes various embodiments of a waterproofgranule coated roofing membrane. One embodiment of the roofing membraneincludes a membrane layer. An adhesive layer is bonded to a first sideof the membrane layer and a layer of roofing granules is adhered to thefirst adhesive layer.

Other advantages of the roofing membrane will become apparent to thoseskilled in the art from the following detailed description, when read inview of the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view of a building structure and an attachedlow-slope roof according to the invention;

FIG. 2 is an enlarged cross-sectional view of an exemplary embodiment ofa granule-coated waterproof roofing membrane;

FIGS. 2A-2C are enlarged cross-sectional views of exemplary embodimentsof reinforced granule-coated waterproof roofing membranes;

FIG. 2D is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane with an adhesionenhancing layer that enhances the adhesion between an adhesive layer anda waterproof membrane layer;

FIG. 2E is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane with a single layer thatboth enhances the adhesion between an adhesive layer and a waterproofmembrane layer and reinforces the waterproof membrane layer;

FIG. 3 is a plan view of an exemplary embodiment of a granule coatedwaterproof roofing membrane having the shape of a three-tab shingle;

FIGS. 4A and 4B illustrate exemplary embodiments of granules havingdifferent shapes;

FIG. 5 is a plan view of an exemplary embodiment of a rectangulargranule coated waterproof roofing membrane having an appearance of athree-tab shingle;

FIG. 5A is a sectional view illustrating one embodiment of therectangular granule coated waterproof roofing membrane illustrated byFIG. 5;

FIG. 5B is a sectional view illustrating another embodiment of therectangular granule coated waterproof roofing membrane illustrated byFIG. 5;

FIG. 6 is an enlarged cross-sectional view of an exemplary embodiment ofa granule-coated waterproof roofing membrane;

FIGS. 7A-7D are enlarged cross-sectional views of exemplary embodimentsof granule-coated waterproof roofing membranes;

FIG. 8 is an enlarged cross-sectional view of an exemplary embodiment ofa granule-coated waterproof roofing membrane;

FIG. 9 is an enlarged cross-sectional view of an exemplary embodiment ofa granule-coated waterproof roofing membrane;

FIG. 10 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane;

FIG. 11 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane;

FIG. 12 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane;

FIG. 13 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane;

FIG. 14 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane;

FIG. 15 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane;

FIG. 16 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane;

FIG. 17 is an enlarged cross-sectional view of an exemplary embodimentof a granule-coated waterproof roofing membrane; and

FIG. 18 is perspective view of a roll of the granule-coated roofingmembrane.

DETAILED DESCRIPTION OF THE INVENTION

The present invention will now be described with occasional reference tothe specific embodiments of the invention. This invention may, however,be embodied in different forms and should not be construed as limited tothe embodiments set forth herein. Rather, these embodiments are providedso that this disclosure will be thorough and complete, and will fullyconvey the scope of the invention to those skilled in the art.

Unless otherwise defined, all technical and scientific terms used hereinhave the same meaning as commonly understood by one of ordinary skill inthe art to which this invention belongs. The terminology used in thedescription of the invention herein is for describing particularembodiments only and is not intended to be limiting of the invention. Asused in the description of the invention and the appended claims, thesingular forms “a,” “an,” and “the” are intended to include the pluralforms as well, unless the context clearly indicates otherwise.

Unless otherwise indicated, all numbers expressing quantities ofingredients, properties such as molecular weight, reaction conditions,and so forth as used in the specification and claims are to beunderstood as being modified in all instances by the term “about.”Accordingly, unless otherwise indicated, the numerical properties setforth in the specification and claims are approximations that may varydepending on the desired properties sought to be obtained in embodimentsof the present invention. Notwithstanding that the numerical ranges andparameters setting forth the broad scope of the invention areapproximations, the numerical values set forth in the specific examplesare reported as precisely as possible. Any numerical values, however,inherently contain certain errors necessarily resulting from error foundin their respective measurements.

As used in this application, the phrase “low-slope roof” is defined as aroof having a slope or pitch within the range of from about ¼:12 toabout 4:12. Proper roof design requires some slope to promote drainageand prevent water ponding. As used in this application, the phrase“steep-slope roof” is defined as a roof having a slope or pitch greaterthan 4:12. Typical steep-slope roofs have a slope or pitch from about4:12 to about 18:12, however, some steep-slope roofs may be evensteeper. Details of typical steep-slope roofs can be found in theAsphalt Roofing Residential Manual, 2006, published by The AsphaltRoofing Manufacturers Association (ARMA). Unless otherwise indicated,the roofing materials described herein can be used in low-slopeapplications and steep-slope applications.

As used in this application, the terms “pitch” and “slope” in thecontext of a building structure roof are defined as the amount of rise aroof has compared to the horizontal measurement of the roof. A roofhaving a slope of 4:12 therefore means that for every 12 inches ofhorizontal measurement, or roof run, the vertical measurement, or roofrise is 4 inches.

Referring now to FIG. 1, a building structure 10 is shown having a steeproof 11 with a shingle-based roofing system 12. While the buildingstructure 10 illustrated in FIG. 1 is a residential home, it will beunderstood that the building structure 10 may be any type of structure,such as a garage, church, arena, an industrial or commercial building,having a steep-slope roof 11 with a shingle-based roofing system 12having a plurality of shingles 14. A low-slope roof 16 extends from thebuilding structure 10 and may cover an open or enclosed patio, garage,or carport, for example. The low-slope roof 16 includes a low-slope roofdeck 18.

FIG. 2 illustrates an exemplary embodiment of a granule-coated roofingmembrane 20. In the example illustrated by FIG. 2, the granule-coatedroofing membrane 20 includes a waterproof membrane layer 22, an adhesive24, and a layer of roofing granules 28. The adhesive 24 adheres to thewaterproof membrane layer 22. The layer of roofing granules 28 isadhered to the waterproof membrane layer 22 by the adhesive 24.

The waterproof membrane layers described in this application may be madefrom a wide variety of different materials. For example, the waterproofmembrane 22 may be any membrane that prevents water on a top side 22A ofthe membrane from passing through the membrane 22 to a bottom side 22Bof the membrane. That is, the waterproof membrane layer 22 may be madefrom any water impermeable material. Examples of materials that thewaterproof membrane layer 22 can be made from include, but are notlimited to, any thermoset material or any thermoplastic material.Examples of thermoset materials that can be used include, but are notlimited to, EPDM (ethylene, propylene, diene monomer rubber), CSPE(chlorosulfonated polyethylene), such as DuPont® Hypalon®, CR(Neoprene), ECR (Epoxy Coated Rebar). Examples of thermoplasticmaterials that can be used include, but are not limited to, polyester,nylon, TPO (Thermoplastic Polyolefin), CPA (Copolymer Alloy), PVC(polyvinylchloride), EIP (Ethylene Interpolymer), NBP (Nitrile Alloy),PIB (Polyisobutylene), and CPE (Chlorinated Polyethylene). Thewaterproof membrane can be made from any combination of thermoset and/orthermoplastic materials, including but not limited to, any combinationof the thermoset and/or thermoplastic materials disclosed by thisapplication. The waterproof membrane layer 22 may be formed as extrudedsheets of any one or any combination of these materials. The material ofthe membrane layer 22 may have fire retardant properties, therebyenhancing the fire retardant properties of the granule-coated roofingmembrane 20. In one exemplary embodiment, the membrane layer is madefrom a ketone ethylene ester resin, such as Dupont™ ELVALOY®,polyvinylchloride (PVC), or a combination of ketone ethylene ester andPVC.

The waterproof membrane layer 22 may be between about 1 and about 120mils thick. In one exemplary embodiment, the waterproof membrane layer22 is about 15-120 mils, such as between about 15 and about 80 mils orabout 45-80 mils. In one exemplary embodiment, when the waterproofmembrane layer 22 is between 1-15 mils, the waterproof membrane layerhas a melting temperature that is greater than 350 degrees F.

The waterproof membrane layer 22 may have a wide variety of differentconfigurations. Referring to FIG. 1, a low-slope roof 16 may use large,rectangular waterproof granule coated membrane sheets 30. For a steepslope roof 11, the waterproof membrane layer 22 may have a smallerrectangular form or may be cut to provide the appearance of atraditional shingle 14. For example, FIG. 3 illustrates that thewaterproof membrane layer 22 may be cut into the shape of a three-tabshingle 300. Such a waterproof membrane layer 300 may be used toconstruct granule coated roofing membranes 20 that provide substantiallythe same appearance as a shingle and can be installed in substantiallythe same manner as a shingle. Individual three-tab shingles 300 may bemade with the waterproof membrane layer as illustrated by FIG. 3 orcontinuous/repeating three-tab shingles 300 may be provided in rollform.

The adhesives described in this application may take a wide variety ofdifferent forms. For example, the adhesive 24 may be any materialcapable of adhering the granules 28 to the waterproof membrane 22.Examples of materials that may be used as an adhesive include, but arenot limited to, asphalt, polymer modified asphalt, butyl basedadhesives, such as polyisobutylene, adhesives that cure by drying, suchas solvent based adhesives and polymer dispersion adhesives, pressuresensitive adhesives, contact adhesives, hot melt adhesives, such asthermoplastic adhesives, and multi-component adhesives, such asacrylics, urethanes, and epoxies. Examples of multi-part adhesivesinclude polyester resin-polyurethane resin, polyols-polyurethane resin,and acrylic polymers-polyurethane resins. When adhesives other thanasphalt based adhesives are used, the adhesive may be dyed or otherwiseprocessed to have the dark or black appearance of asphalt.

In one exemplary embodiment, the granule holding function of theadhesive layer 24 is provided by the waterproof membrane 22 itself, sothat a separate adhesive layer is not required. For example, thewaterproof membrane 22 may be heated to provide the waterproof membrane22 with adhesive properties. Granules 28 can then be applied to thewaterproof membrane. For example, the granules can be pressed into theadhesive. In another exemplary embodiment, the granules 28 are heatedand pressed into the surface of the membrane 22. The heat from thegranules 28 causes the waterproof membrane to melt or partially meltaround the granules. In either case (membrane heating and/or granuleheating), when the waterproof membrane 22 and/or the granules 28 cool,the granules 28 are permanently adhered to the membrane 22.

When the adhesive(s) disclosed in this application is an asphalt, theasphalt may be any asphalt-based material capable of adhering thegranules 28 to the waterproof membrane 22 and/or capable of adhering thewaterproof membrane 22 to a roof deck. In one exemplary embodiment, theasphalt is not modified with a polymer. In another exemplary embodiment,the asphalt is polymer modified asphalt. The asphalt may be modified byany suitable polymer, such as with styrene-butadiene-styrene (SBS), orstyrene-isoprene-styrene (SIS). Examples of polymer modified asphaltsare disclosed in U.S. Pat. No. 4,738,884 to Algrim et al. and U.S. Pat.No. 3,770,559, to Jackson the contents of which are incorporated hereinby reference in their entirety. The asphalt used as the adhesive layer24 may include various types or grades of asphalt, including flux,paving grade asphalt blends, propane washed asphalt, oxidized asphalts,and/or blends thereof. Effective blends of asphalt or bituminousmaterials are understood by those of ordinary skill in the art. Thesepolymer modified asphalts may also include fillers. For example, thefirst adhesive layer 24 may include a filler of finely ground inorganicparticulate matter, such as ground limestone, dolomite or silica, talc,sand, or calcium carbonate in an amount within the range of from about25 percent to about 60 percent by weight of the first adhesive layer 24.Other materials suitable for use in an asphalt adhesive layer includeprocess oils, tackifying resins, and other types of natural andsynthetic rubber materials and thermoplastic polymers. Additionally,recycled roof tear-off materials, such as shingles, may be included inthe asphalt adhesive. Recycled shingles may be processed in a widevariety of different ways to allow the material to be used in theadhesive. For example, tear off shingles may be processed as describedin U.S. Patent Application 20110049275 to Zickell, to be used as afiller or an additive to the adhesive layer 24.

The adhesive layer 24 can be applied to the substrate 22 in a widevariety of different manners. In one exemplary embodiment, the adhesivelayer may be between about 10 mils and about 100 mils or may be betweenabout 15 mils and about 100 mils. The adhesive layer 24 may be appliedto the entire upper surface 22A of the substrate 22 or only portions ofthe substrate. For example, the adhesive layer 24 may be applied to thearea of the roofing material 20 that is exposed (i.e. the area that isnot covered by other roofing material 20) and the adhesive layer 24 isnot applied to the unexposed area (i.e. the area that is covered byother roofing material 20) or a portion of the unexposed area.

The roofing granules 28 may take a wide variety of different forms. Inan exemplary embodiment, the roofing granules are dense, non-porous,UV-ray resistant, natural mineral particles coated in ceramic. Themineral particles may be silica rich minerals, such as rhyolite. Coloredpigments may be applied to the base mineral by the ceramic coating thatcovers the granule. Roofing granules are available from 3M.

Any desired color, color blend, or combinations of colors and colorblends of granules may be applied to define the layer of roofinggranules 28. Advantageously, the granule-coated roofing membrane 20 maybe manufactured to include colors and/or color blends of granules 28that match, coordinate with, and/or complement the colors and/or colorblends of the granules of the roofing shingles 14 installed on otherportions of the building structure 10. For example, in one exemplaryembodiment, the traditional shingles 14 are used on one portion of thebuilding and the roofing material 20 is used on another portion of thebuilding. By matching, coordinating with, and/or complementing thecolors and/or color blends of the granules of the roofing shingles 14with the granule-coated roofing material 20, an aesthetically pleasingappearance is achieved.

The waterproof membrane 22 provides flexibility in the selection of thegranules 28 that may be used on the roofing material 20. Since thewaterproof membrane provides the waterproofing and/or water sheddingfeature of the roofing material 20, the granules 28 may be selected toprovide an aesthetically pleasing appearance without needing to meet thehigh performance requirements of granules of conventional shingles. Forexample, granules that are not typically used in roofing applicationsmay be used.

As is mentioned above, traditional roofing granules are UV-rayresistant/UV opaque and have a ceramic coating. The UV resistance andthe ceramic coating protects the asphalt of traditional shingles. If awaterproof membrane 22 and/or adhesive 24 do not need to be protectedfrom UV rays, granules that are not traditionally used in roofingapplications can be used. For example, granules that are not UV opaqueand/or that are not coated in ceramic can be used. Examples of granulesthat are not traditionally exposed in roofing applications that may beused with the waterproof membrane 22 include, but are not limited touncoated mineral particles, such as rhyolite and other silica richminerals, rock dust, and coal slag.

The roofing granules 28 may have a variety of different sizes. In oneexemplary embodiment, the size and/or shape of the granules 28 used onthe roofing material 20 is different than the size and/or shape of thegranules used of the corresponding conventional shingles 14. Forexample, the average size of the granules used on the roofing material20 are about 10%, about 20%, about 30%, about 40%, about 50%, or between10% and 50% larger or smaller than the average size of the granules of acorresponding conventional shingle.

Referring to FIG. 4A, the granules of a traditional shingle may haveroughly equivalent length L₁, height H₁, and width W₁ dimensions.Referring to FIG. 4B, the granules 28 of the roofing material 20 may beselected to have a shorter height dimension H₂ vs. a wider widthdimension W₂ and/or a longer length dimension L₂ (i.e. flatter granule).This allows fewer granules and less granule material to be used on theroofing material 20 as compared to a traditional shingle 14. Forexample, a ratio R of granule height H over granule width W and granulelength L:

R=H/(W+L)

of the granules for the roofing material 20 may be significantly lowerthan the ratio for the granules of a traditional shingle. For example,the average ratio R₂ of the granules used on the roofing material 20 areabout 10%, about 20%, about 30%, about 40%, about 50%, or between 10%and 50% less than the ratio R₁ for the granules of a correspondingconventional shingle.

Roofing granules used to define the layer of roofing granules 28 may beapplied to the first adhesive layer 24 by any desired method. Examplesof methods and apparatus for applying roofing granules to an asphaltcoated sheet are disclosed in U.S. Pat. No. 5,746,830 to Burton et al.,U.S. Pat. No. 6,228,422 to White et al., U.S. Pat. No. 6,610,147 toAschenbeck, and U.S. Pat. No. 7,163,716 to Aschenbeck, each of which isincorporated herein by reference in their entirety.

The layer of roofing granules 28 can be applied to the substrate 22 in awide variety of different manners. The layer of roofing granules 28 maybe applied to the adhesive coating 24 or only portions of the adhesivecoating. For example, the layer of granules may be applied to the areaof the roofing material 20 that is exposed (i.e. the area that is notcovered by other roofing material 20) and the layer of granules is notapplied to the unexposed area (i.e. the area that is covered by otherroofing material 20) or a portion of the unexposed area.

The layer of granules 28 can be applied in a manner that provides theroofing material 20 with a desired appearance. For example, referring toFIG. 5 the adhesive 24 and/or the roofing granules 28 can be applied toan uncut rectangular substrate 400 to provide the appearance of atraditional three-tab shingle. Areas 402 having the appearance of thecuts between tabs 404 can be provided by applying darker or blackgranules 28 in the areas 402, masking, applying mineral dust, orotherwise preventing the layer of granules 28 from being applied in theareas (See FIG. 5B), and/or masking, applying mineral dust, or otherwisepreventing the granules and adhesive 24 from being provided in the areas402 (See FIG. 5A). In one embodiment, the adhesive 24 may be applied tothe entire tab region 404 of the roofing material and a mineral dust 406or other material that prevents adhesion of the granules is deposited inthe areas 400 (See FIG. 5B). A wide variety of different appearances canbe provided by the roofing material 20, without cutting a rectangularshaped substrate 22, by controlling the application of the adhesive 24and/or granules.

Referring to FIGS. 2A-2C, in one exemplary embodiment, the physicalproperties of the membrane layer 22 may be enhanced by a reinforcinglayer 200. The membrane layer 22 may be applied to the reinforcing layer200 or the reinforcing layer 200 may be applied to the membrane layer 22in a wide variety of different ways. In FIG. 2A, the reinforcing layer200 is on the top surface 22A of the waterproof membrane layer 22. InFIG. 2B, the waterproof membrane layer 22 is on the reinforcing layer200. In FIG. 2C, the reinforcing layer 200 is inside the waterproofmembrane layer 22 or between two waterproof membrane layers.

The reinforcing layer 200 can be made from a wide variety of differentmaterials. Any material that increases the physical properties, such astear strength, tensile strength, and/or puncture resistance of thegranule coated waterproof membrane 20 can be used. Examples of suitablematerials that the reinforcing layer 200 can be made from include, butare not limited to, woven, knitted, or nonwoven glass, polyester, orcombinations thereof. An example of a knitted material is a weftinserted fabric. The reinforcing layer 200 can be applied to thewaterproof membrane layer 22 in a variety of different ways. Forexample, the reinforcing layer 200 can be fused to the waterproofmembrane layer 22 or an adhesive, such as a polymeric adhesive, can beused to adhere the reinforcing layer 200 to the waterproof membranelayer 22.

The combination of the reinforcing material and material of thewaterproof membrane 22 provides improved breaking strength, tearingstrength, and puncture resistance. Additionally, the material of themembrane layer 22 and/or the reinforcing layer 200 may have fireretardant properties.

In one exemplary embodiment, the waterproof membrane layer 22 and thereinforcing layer 200 are configured to have a much higher “nail pullthrough” force than a conventional shingle 14. Shingles are typicallysecured to a roof deck with nails. The nail pull through force is theamount of force required to pull the shingle material over the head ofthe nail. ASTM D3462 requires conventional shingles to pass a minimum of20 lbf nail pull test. The nail pull through force for some conventionalshingles with an unreinforced nail zone is about 40 lbf. In oneexemplary embodiment, the nail pull through force for a granule coatedsubstrate 20 having a woven or knitted reinforcement layer 200 on a rearsurface 22A of the membrane layer is over 100 lbf, may be over 140 lbf,and may be over 200 lbf. In exemplary embodiments, the nail pull throughforce for a granule coated substrate 20 having a woven or knittedreinforcement layer 200 is over 7 times, over 8 times, over 9 times, orover ten times the nail pull through force for a conventional shinglewith an unreinforced nail zone.

In one exemplary embodiment, the waterproof membrane layer 22 and thereinforcing layer 200 are configured to have a much higher punctureresistance than a conventional shingle 14. The puncture resistance forsome conventional low-slope roofing materials is about 20 to 50 lbf. Inone exemplary embodiment, the puncture resistance for a granule coatedsubstrate 20 having a woven or knitted reinforcement layer 200 is over175 lbf, such as from about 175 lbf to about 250 lbf. In exemplaryembodiments, the puncture resistance for a granule coated substrate 20having a woven or knitted reinforcement layer is about five times toabout ten times the puncture resistance for a conventional low-sloperoofing material.

In one embodiment, the membrane layer 22 is the FIBERTITE® membraneproduct manufactured by Seaman Corporation of Wooster, Ohio. (Seehttp://fibertite.com/home.php, accessed Sep. 2, 2011). In thisembodiment, the membrane consists of a woven or knitted fabric layercoated with an adhesive and a proprietary blend of DuPont ELVALOY®ketone ethylene ester (KEE) resin. In this alternate embodiment, theresin may be applied to one or both sides; i.e., the broad faces, of thewoven or knitted fabric layer and may impregnate the woven or knittedfabric layer.

Referring to FIG. 2D, in one exemplary embodiment, the adhesion betweenthe membrane layer 22 and the adhesive 24 may be enhanced by an adhesionpromoting layer 300. The adhesion promoting layer 300 can take a widevariety of different forms. The adhesion promoting layer 300 provides atextured multi-dimensional surface which optimizes adhesion with asphaltor other adhesive 24 for the exposed surface of the granule coatedwaterproof membrane 20. In an exemplary embodiment, the adhesionpromoting layer 300 is bonded to the membrane layer 22. The adhesionpromoting layer 300 can be bonded to the waterproof membrane layer 22 ina variety of different ways. For example, the adhesion promoting layer300 can be fused to the waterproof membrane layer 22 or an adhesive,such as a polymeric adhesive, can be used to adhere the adhesionpromoting layer 300 to the waterproof membrane layer 22. The illustratedadhesion promoting layer 300 includes discrete projections 302, strands,or other surfaces that extend into the adhesive 24 to promote a strongbond between adhesion promoting layer 300 and the adhesive 24.

Examples of materials that can be used for the adhesion promoting layer300 include, but are not limited to felt material, such as polyesternon-woven fleece, texturized yarns, bare yarn, and any other materialthat provides a textured surface for better mechanical adhesion of theadhesive to the membrane 22.

Referring to FIG. 2E, in one exemplary embodiment the functions of theadhesion promoting layer 300 and the reinforcing layer 200 may beprovided by a single layer. For example, a surface 250 of one of thereinforcing layers 200 described above may be treated or processed toprovide discrete projections 302 or strands that promote adhesion.Further, a non-woven reinforcement layer 200 may already havecharacteristics that also make the layer a good adhesion promotinglayer. A woven or knitted reinforcement layer 200 have the surface 250that contacts the adhesive 24 processed to provide adhesion promotingproperties. For example, the surface 250 of the woven or knittedreinforcement layer may be initially formed with extending projectionsor strands, or may be abraded, scuffed, grated or cut to provideprojections or strands that promote adhesion.

The reinforcement layer 200 may include strands of textured yarns, suchas textured polyester yarns. Air textured yarn is a yarn that has beenprocessed to introduce durable crimps, coils, loops or other finedistortions along the length of the fibers, thereby altering the surfacetexture and topography of the reinforcement layer fabric. The texturingprocess may include one or more of the following processes: twistingyarn, heat-setting and then untwisting; passing the yarn through aheated “stuffer box”; passing the heating yarn over a knife edge;passing the heated yarn between a pair of geared wheels or some similardevice; and knitting the yarn into a fabric reinforcement layer,heat-setting, then unraveling the yarn. The use of air textured yarn inthe reinforcement layer 200 improves adhesion of asphalt, or otheradhesive 24 to the waterproof membrane 22. As such, a woven or knittedreinforcement layer may be selected to both promote adhesion andreinforce the membrane layer 22.

In one exemplary embodiment, the waterproof membrane 22 may be processedto perform the functions of the adhesion promoting layer 300 and therebyeliminate an adhesion promoting layer made from discrete materials. Forexample, a surface 22A or 22B of the waterproof membrane 22 may betreated or processed to provide discrete projections or strands thatpromote adhesion. For example, a surface of the waterproof membranelayer may be initially formed with projections or strands, or may beabraded, scuffed, grated or cut to provide projections or strands thatpromote adhesion.

The layers of granules 28, adhesive 24, waterproof membranes 22,reinforcement layers 200, and/or adhesion promoting layers 300 disclosedherein can be combined in a variety of different ways to construct manydifferent granule coated waterproof membranes 20. FIGS. 6-11 illustratesome of the possible configurations.

In FIG. 6, a first adhesive layer 24 is applied to a first side 22A ofthe membrane layer 22 (upwardly facing surface when installed on aroof). A second adhesive layer 26 is applied to a second side 22B of themembrane layer 22 (downwardly facing surface when installed on a roof).A layer of roofing granules 28 is applied to the first adhesive layer 24and defines a granule-coated surface 30.

A release layer 32 is applied to the second adhesive layer 26. Therelease layer may take a wide variety of different forms. The releaselayer 32 can be any material that removably adheres to the secondadhesive layer 26. Examples of acceptable materials for the releaselayer 32 include, but are not limited to, plastic materials, such asplastic films (i.e. polyolefin film, polypropelyne film, etc.), coatedmaterials, such as paper, plastic or other material coated with siliconeor other release material. The release layer 32 prevents thegranule-coated roofing membrane 20 from adhering to itself when arrangedin a roll 34 (See FIG. 18), as described below or when sheets of thegranule coated roofing membrane 22 are stacked. The release layer 32 maybe removed by a roof installer so that the bottom surface, or surfaceopposite the granule-coated surface 30 of granule-coated roofingmembrane 20, will adhere to the low-slope roof deck 18 or steep-sloperoof as shown in FIG. 1.

The second adhesive layer 26 may be identical to the first adhesivelayer 24. In the embodiments disclosed herein, the second adhesive layer26 is provided to adhere or bond the granule-coated roofing membrane 20to the low-slope roof deck 18 or the steep-slope roof 11. Alternatively,the second adhesive layer 26 may be a softer asphalt material relativeto the asphalt material of the first adhesive layer 24. The secondadhesive layer 26 may also contain more light oil relative to the firstadhesive layer 24, therefore making the second adhesive layer 26 softer,more flexible, and have stronger or better adhesion properties than thefirst adhesive layer 24. One method of applying a relativelynon-adhesive asphaltic material and an adhesive asphalt coating to awoven or non-woven fibrous mat is disclosed in U.S. Pat. No. 6,296,912to Zickell, which is incorporated herein by reference in its entirety.

It will be understood that the second adhesive layer 26 is not requiredand that the granule-coated roofing membrane 20 may be manufacturedwithout the second adhesive layer 26. In an embodiment without thesecond adhesive layer 26, the granule-coated roofing membrane 20 may beattached to the low-slope roof deck 18 or steep-slope roof deck, or anylayer of material intermediate the low-slope roof deck 18 or steep-sloperoof deck and the granule-coated roofing membrane 20, by any desiredmeans. For example, the granule-coated roofing membrane 20 may beattached to the low-slope roof deck 18 with an adhesive applied to anyone or more of the low-slope roof deck 18, the membrane layer 22, and anintermediate layer of material. The granule-coated roofing membrane 20may also be attached to the low-slope roof deck 18 or steep-slope roofdeck with mechanical fasteners.

In the example illustrated by FIGS. 7A-7D, the granule coated waterproofmembrane 20 includes a layer of granules 28, a first adhesive layer 24,such as a first asphalt adhesive layer, an adhesion promoting layer 300,a waterproof membrane 22, and a reinforcement layer 200. In the exampleillustrated by FIG. 7B, the granule coated waterproof membrane 20 alsoincludes a second adhesive layer 26, such as a second asphalt adhesivelayer. Referring to FIG. 7C, in an exemplary embodiment, the surface 250of the reinforcement layer 200 is configured to promote adhesion of thereinforcement layer 200 to the second adhesive layer 26. For example, inFIG. 7C the surface 250 is illustrated as having strands or projections302. FIG. 7D is an embodiment that is similar to the embodiment of FIG.7C, except the adhesion promoting layer 300, the waterproof membrane 22,and the reinforcement layer 200 are flipped. That is, in the FIG. 7Cembodiment, the reinforcement layer 200 is on top of the waterproofmembrane 22 and the adhesion promoting layer is on the bottom of thewaterproof membrane 22.

FIG. 8 illustrates exemplary embodiments of self adhering, waterproof,granule coated roofing membranes 800. The following is a description ofthe different layers illustrated by FIG. 8:

801—Roofing Granules, such as the roofing granules 28 described herein.

802—Adhesive, such as the layer of adhesive 24 described herein.

803—Adhesion promoting material, such as the adhesion promoting layer300 described herein.

804—Waterproof membrane material, such as the waterproof membranematerial 22 described herein.

806—Reinforcement material, such as the reinforcement layer 200described herein.

805—Adhesive, such as a polymer adhesive, which may be apolyvinylchloride adhesive, for adhering the layer 806 to the layer 804.

808—Adhesion promoting material, such as the adhesion promoting layer300 described herein.

807—Adhesive, such as a polymer adhesive, which may be apolyvinylchloride adhesive, for adhering the layer 808 to the layer 806.

809—Adhesive, such as the layer of adhesive 26 described herein.

Any combination of the layers illustrated by FIG. 8 can be used to makea variety of different self adhering, waterproof, granule coated roofingmembranes 800. The rows of the following table identify some of thepossible combinations. An “X” in a cell of each row indicates thepresence of each layer in the example indicated by the row. A cellwithout an “X” indicates that the layer is not included in the exampleindicated by the row.

Layer Layer Layer Layer Layer Layer Layer Layer Layer 801 802 803 804805 806 807 808 809 X X X X X X X X X X X X X X X X X X X X X X X X X XX X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X

FIG. 9 illustrates exemplary embodiments of fastener (for example,nails) applied, waterproof, granule coated roofing membranes 900. Thefollowing is a description of the different layers illustrated by FIG.9:

901—Roofing Granules, such as the roofing granules 28 described herein.

902—Adhesive, such as the layer of adhesive 24 described herein.

903—Adhesion promoting material, such as the adhesion promoting layer300 described herein.

904—Waterproof membrane material, such as the waterproof membranematerial 22 described herein.

906—Reinforcement material, such as the reinforcement layer 200described herein.

905—Adhesive, such as a polymer adhesive, which may be apolyvinylchloride adhesive, for adhering the layer 906 to the layer 904.

908—Waterproof membrane material, such as the waterproof membranematerial 22 described herein.

907—Adhesive, such as a polymer adhesive, which may be apolyvinylchloride adhesive, for adhering the layer 908 to the layer 906.

Any combination of the layers illustrated by FIG. 9 can be used to makea variety of different fastening, waterproof, granule coated roofingmembranes 900. The rows of the following table identify some of thepossible combinations. An “X” in a cell of each row indicates thepresence of each layer in the example indicated by the row. A cellwithout an “X” indicates that the layer is not included in the exampleindicated by the row.

Layer Layer Layer Layer Layer Layer Layer Layer 901 902 903 904 905 906907 908 X X X X X X X X X X X X X X X X X X X X X

FIG. 10 illustrates additional exemplary embodiments of self adhering,waterproof, granule coated roofing membranes 1000. The following is adescription of the different layers illustrated by FIG. 10:

1001—Roofing Granules, such as the roofing granules 28 described herein.

1002—Adhesive, such as the layer of adhesive 24 described herein.

1003—Adhesion promoting material, such as the adhesion promoting layer300 described herein.

1004—Waterproof membrane material, such as the waterproof membranematerial 22 described herein.

1005—Reinforcement material, such as the reinforcement layer 200described herein.

1006—Waterproof membrane material, such as the waterproof membranematerial 22 described herein.

1007—Adhesion promoting material, such as the adhesion promoting layer300 described herein.

1008—Adhesive, such as the layer of adhesive 26 described herein.

Any combination of the layers illustrated by FIG. 10 can be used to makea variety of different self adhering, waterproof, granule coated roofingmembranes 1000. The rows of the following table identify some of thepossible combinations. An “X” in a cell of each row indicates thepresence of each layer in the example indicated by the row. In FIG. 10,it should be noted that when reinforcement layer 1005 is removed, theresulting depicted configuration implies a single membrane layer (i.e.layers 1004 and 1006 merge). A cell without an “X” indicates that thelayer is not included in the example indicated by the row.

Layer Layer Layer Layer Layer Layer Layer Layer 1001 1002 1003 1004 10051006 1007 1008 X X X X X X X X X X X X X X X X X X X X X X X X X X X X XX X X X X X X X X X X X X X X X X X X X X X X

FIG. 11 illustrates exemplary embodiments of fastener (for example,nails) applied, waterproof, granule coated roofing membranes 1100. Thefollowing is a description of the different layers illustrated by FIG.11:

1101—Roofing Granules, such as the roofing granules 28 described herein.

1102—Adhesive, such as the layer of adhesive 24 described herein.

1103—Adhesion promoting material, such as the adhesion promoting layer300 described herein.

1104—Waterproof membrane material, such as the waterproof membranematerial 22 described herein.

1105—Reinforcement material, such as the reinforcement layer 200described herein.

1106—Waterproof membrane material, such as the waterproof membranematerial 22 described herein.

Any combination of the layers illustrated by FIG. 11 can be used to makea variety of different fastening, waterproof, granule coated roofingmembranes 1100. The rows of the following table identify some of thepossible combinations. An “X” in a cell of each row indicates thepresence of each layer in the example indicated by the row. In FIG. 11,it should be noted that when reinforcement layer 1105 is removed, theresulting depicted configuration implies a single membrane layer (i.e.layers 1104 and 1106 merge). A cell without an “X” indicates that thelayer is not included in the example indicated by the row.

Layer Layer Layer Layer Layer Layer 1101 1102 1103 1104 1105 1106 X X XX X X X X X X X X X X X X X X X X

The granule coated waterproof roofing membrane may be formed in a widevariety of different ways. In one exemplary embodiment, thegranule-coated roofing membrane 20 is formed using a continuousmanufacturing process. For example, the membrane layer 22 may beprovided as a continuous sheet of material having a width W of about 3feet (See FIG. 18). It will be understood that the membrane layer 22 mayhave any other desired width. The width W of the membrane layer 22 willbe determined by the intended use of the finished granule-coatedwaterproof roofing membrane 20. For example, for residential buildingapplications, the membrane layer 22 may have a width within the range offrom about 2 feet to about 5 feet. For commercial building applications,the membrane layer 22 may have a much larger width, such as within therange of from about 6 feet to about 12 feet. The membrane layer 22 mayhave any other desired width, such as a width smaller than about 2 feetand a width larger than about 12 feet.

In a first step of the manufacturing process, the first adhesive layer24 and the second adhesive layer 26 may be applied to the first side 22Aand the second side 22B, respectively, of the membrane layer 22. Asdiscussed above, one method of applying a relatively non-adhesiveasphaltic material and an adhesive asphalt coating; i.e., the firstadhesive layer 24 and the second adhesive layer 26, to a woven ornon-woven fibrous mat is disclosed in U.S. Pat. No. 6,296,912 toZickell. In an exemplary embodiment, the method disclosed by Zickell isadapted to apply the first adhesive layer 24 and the second adhesivelayer 26 to the waterproof membrane 22.

Granules 28 may then be applied to the first adhesive layer 24, therebydefining the granule-coated roofing membrane 20. As discussed above,various examples of methods and apparatus for applying roofing granulesto an asphalt coated sheet are disclosed in U.S. Pat. No. 5,746,830 toBurton et al., U.S. Pat. No. 6,228,422 to White et al., U.S. Pat. No.6,610,147 to Aschenbeck, and U.S. Pat. No. 7,163,716 to Aschenbeck.

If desired, the release layer 32 may then be applied to the secondadhesive layer 26. The release layer 32 may be applied to the secondadhesive layer 26 before, after, or concurrently with the application ofgranules 28 to the first adhesive layer 24.

The granule-coated roofing membrane 20 may then be wound into a roll 34,as shown in FIG. 18. The roll 34 of the granule-coated roofing membrane20 may have any desired diameter. Alternatively, the granule-coatedroofing membrane 20 may be cut to discrete lengths and stacked forsubsequent packaging and shipping.

Advantageously, the granule-coated surface 30 of the granule-coatedroofing membrane 20 may be manufactured to include colors and/or colorblends of granules 28 that match, coordinate with, and/or complement thecolors and/or color blends of the granules of the roofing shingles 14installed on the building structure 10. By matching, coordinating with,and/or complementing the colors and/or color blends of the granules ofthe roofing shingles 14 with the granule-coated roofing membrane 20, anaesthetically pleasing appearance is achieved.

The granule-coated surface 30 of the granule-coated roofing membrane 20may prevent any unevenness in the underlying low-slope roof deck 18 fromtelegraphing through the granule-coated roofing membrane 20 by maskingany such unevenness. The granule-coated roofing membrane 20 may haveimproved weathering performance. In one exemplary embodiment, theaddition of ceramic-coated granules to asphaltic roofing materialsenhances weathering performance by providing UV protection for theunderlying asphalt base. The life expectancy of a typical steep-slopeshingle is typically 15 to 20 years or more. Likewise, typicalcommercial roofing membranes are known to withstand the effects ofweather and perform satisfactorily over as many as 10 to 20 years. Bycombining a robust membrane and ceramic-coated roofing granules, theweathering performance of the granule-coated roofing membrane 20 of thepresent invention will be improved relative to a typical low-slope andsteep-slope roofing products.

EXAMPLES

In the following examples, various membrane configurations were suppliedby Seaman Corporation. These membranes were coated on a commercialroofing line operated by Northern Elastomerics, Inc. in Brentwood N.H.Coating consisted of a first asphalt layer 24 on the upper surfacefollowed by a second asphalt layer 26 on the lower surface. Once coated,standard roofing granules 28 supplied by Grantech Inc., were applied tothe first asphalt coating 24. A siliconized polyethylene release liner32 was applied to the second asphalt coating. The final product was cutto length and packaged prior to testing.

Tables 1-4 reflect properties of examples of six granule-coated roofingmembranes made in accordance with the present application. All testingis performed at 23° C.+/−2° C. Puncture testing is based on a modifiedversion of ASTM D5602. Modifications include use of an instrumentedtensile tester with a ½″ radius steel probe at a penetration rate of ½″per minute. Sample size is 4″ square, and is held in place with a metalframe having a 2.5″ diameter circular, central open area. Testing isdone such that the probe penetrates the granule side. Tensile Testingand Tear Testing are based on requirements of ASTM D5147. GranuleEmbedment (also referred to as granule adhesion, scrubs, or granuleloss) is based on ASTM D4977.

Example 1

FIG. 12 schematically illustrates the roofing membrane 1200 ofExample 1. The roofing membrane 1200 shown as 1 in Tables 1-4 wasproduced using an 18 to 20 oz./sq. yd. weft-inserted polyesterreinforcement 1202. A PVC based adhesive compound 1204 was coated on thetop side of the reinforcement 1202, but not on the bottom side. Anadditional PVC/Elvaloy blend 1206 was coated on the top, weathering,surface. Total thickness of this construction (1202+1204+1206) wasapproximately 24 mils. In comparison to Example 6 in Table 1, noadhesive was placed on the bottom side to improve mechanical adhesion ofthe asphaltic adhesive coating 26.

Example 2

FIG. 13 schematically illustrates the roofing membrane 1300 of Example2. The roofing membrane 1300 shown as 2 in Tables 1-4 was produced usingan 18 to 20 oz./sq. yd. weft-inserted polyester reinforcement 1302. Theyarns used for the reinforcement structure included a texturizedpolyester yarn. A PVC based adhesive compound 1204 was coated on the topside of the membrane, but not on the bottom side. An additionalPVC/Elvaloy blend 1206 was coated on the top, weathering, surface. Totalthickness of this construction (1302+1204+1206) was approximately 27mils. In comparison to 1, a texturized yarn of the polyesterreinforcement 1302 was used to provide a “fuzzy” or stranded surface formechanical adhesion of the asphaltic adhesive coating 26.

Example 3

FIG. 14 schematically illustrates the roofing membrane 1400 of Example3. The roofing membrane 1400 shown as 3 in Tables 1-4 was produced usingan 18 to 20 oz./sq. yd. weft-inserted polyester reinforcement 1202identical to that used in 1. A PVC based adhesive compound 1204 wascoated on the top side of the membrane, but not on the bottom side. Anadditional PVC/Elvaloy blend 1206 was coated on the top surface. Apolyester fleece 1408 was then adhered to the top surface. Totalthickness of this construction (1202+1204+1206+1408) was approximately40 mils. In comparison to 1, the additional fleece was used to provide a“fuzzy” or stranded top surface to promote mechanical adhesion of theasphaltic adhesive coating 24.

Example 4

FIG. 15 schematically illustrates the roofing membrane 1500 of Example4. The roofing membrane 1500 shown as 4 in Tables 1-4 was produced usingan 18 to 20 oz./sq. yd. weft-inserted polyester reinforcement 1302identical to that used in 2. The yarns used for the reinforcementstructure included a texturized polyester yarn. A PVC based adhesivecompound 1204 was coated on the top side of the membrane, but not on thebottom side. An additional PVC/Elvaloy blend 1206 was coated on the topsurface. A polyester fleece 1408 was then adhered to the top surface.Total thickness of this construction (1302+1204+1206+1408) wasapproximately 40 mils. In comparison to 2, the additional fleece wasused to provide a “fuzzy” top surface to promote mechanical adhesion ofthe asphaltic adhesive coating 24.

Example 5

FIG. 16 schematically illustrates the roofing membrane 1600 of Example5. The roofing membrane 1600 shown as 5 in Tables 1-4 was produced usinga 24 oz./sq. yd. woven or knitted polyester reinforcement 1602. A PVCbased adhesive compound 1204 was coated on the top side of the membrane,but not on the bottom side. This modified reinforcement 1602 designprovided a tighter weave, preventing bleed-through of the adhesivecompound to the back-side of the membrane. An additional PVC/Elvaloyblend 1206 was coated on the top surface. A polyester fleece 1408 wasthen adhered to the top surface. Total thickness (1602+1204+1206+1408)of this construction was approximately 40 mils. In comparison to 1, theadditional fleece was used to provide a “fuzzy” or stranded top surfaceto promote mechanical adhesion of the asphaltic adhesive coating 24, andthe tighter weave provided for a bottom surface virtually free ofadhesive compound (caused by bleed-through of the calendering process).

Example 6

FIG. 17 schematically illustrates the roofing membrane 1700 of Example6. The roofing membrane 1700 shown as 6 in Tables 1-4 was produced usingan 18 to 20 oz./sq. yd. weft-inserted polyester reinforcement 1202. APVC based adhesive compound 1204, 1704 was coated on the top and bottomsides of the membrane. An additional PVC/Elvaloy blend 1206 was coatedon the top, weathering, surface. Total thickness of this construction(1202+1204+1206+1704) was approximately 27 mils.

Testing of physical properties of these granule-coated roofing membranesis summarized in Table 1. The thicknesses and weights of the granulecoated waterproof membranes and the layers of the granule coatedwaterproof membranes is summarized in Tables 2-4.

TABLE 1 Physical Properties of Example Granule Coated Membranes GranuleTensile Tear Granule Coated Puncture (lbf/in) (lbf) Embedment Membrane(lbf) CD MD CD MD (g) 1 230 230 280 250 230 1.82 2 190 200 300 140 2001.52 3 290 300 360 340 330 4.23 4 240 210 370 200 330 3.34 5 250 270 320310 360 1.72 6 250 260 310 210 200 3.12

TABLE 2 Granule Coated Waterproof Roofing Membrane Thickness & WeightGranule Coated Thickness Sq Ft Wt Membrane (mils) (lbs/sq ft) 1 122.10.84 2 125.5 0.85 3 148.4 0.78 4 136.5 0.70 5 148.5 0.82 6 132.2 0.92

TABLE 3 Reinforced Waterproof Membrane Thickness & Weight ReinforcedWaterproof Membrane Thickness Sq Ft Wt Construction (mils) (lbs/sq ft) 124.8 0.135 2 26.8 0.129 3 49.6 0.171 4 48.6 0.177 5 48.2 0.166 6 28.00.170

TABLE 4 Granule Coated Roofing Membrane Composition Thicknesses (AverageValues) Top Reinforced Adhesive + Waterproof Bottom Granules membraneadhesive layer Example (mils) (mils) (mils) 1 91.8 24.8 5.5 2 91.7 26.87.0 3 88.8 49.6 10.0 4 70.2 48.6 17.7 5 80.5 48.2 19.8 6 95.9 28.0 8.3

Additionally, granule-coated roofing membrane of the present inventionmay be formed as a single ply, thereby resulting in reduced material andlabor costs relative to typical multi-ply low-slope and steep-sloperoofing products.

The principle and mode of operation of the granule-coated waterproofroofing membrane have been described in its preferred embodiments.However, it should be noted that the granule-coated waterproof roofingmembranes described herein may be practiced otherwise than asspecifically illustrated and described without departing from its scope.

1-18. (canceled)
 19. A granule coated waterproof membrane, comprising: aplastic waterproof membrane layer; a reinforcement layer positionedinside the plastic waterproof membrane layer; an adhesive layer having afirst surface and a second surface, wherein the first surface is adheredto a first side of the waterproof membrane layer; and a layer of roofinggranules adhered to the second surface of the adhesive layer.
 20. Theroofing membrane according to claim 19, wherein the waterproof membranelayer is formed substantially from at least one of: ketone ethyleneester (KEE) resin, polyvinyl chloride (PVC), ethylene propylene dienemonomer rubber (EPDM), and thermoplastic polyolefin (TPO).
 21. Theroofing membrane according to claim 19, wherein the reinforcement layeris a woven or knitted fibrous material.
 22. The roofing membraneaccording to claim 21, wherein the woven or knitted fibrous material isformed from at least one of polyester fiber, glass fiber, andcombinations thereof.
 23. The roofing membrane according to claim 19,wherein the reinforcement layer is a non-woven glass fiber material. 24.The roofing membrane according to claim 23, wherein the non-woven orknitted fibrous material is formed from glass fibers.
 25. The roofingmembrane according to claim 19, wherein the waterproof membrane layer isformed substantially from a blend of ketone ethylene ester and polyvinylchloride.
 26. The roofing membrane according to claim 19, wherein theadhesive layer comprises asphalt.
 27. The roofing membrane according toclaim 26, wherein the asphalt of the adhesive layer is a polymermodified asphalt.
 28. The roofing membrane according to claim 27,wherein the polymer modified asphalt includes one ofstyrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS),styrene-butadiene (SB), and blends thereof.
 29. The roofing membraneaccording to claim 28, wherein the polymer modified asphalt furthercomprises at least one of a thermoplastic polymer and a thermoplasticpolyolefin.
 30. The roofing membrane according to claim 29, wherein thepolymer modified asphalt further comprises at least one of polyethylene,polypropylene, an ethylene-propylene copolymer, limestone, dolomite,talc, recycled roofing material, tackifying resin, process oil, and wax.31. The roofing membrane according to claim 19, wherein the roofingmembrane has a puncture resistance of 1751 bf or greater.
 32. Theroofing membrane according to claim 19, wherein the roofing membrane hasa puncture resistance between about 1751 bf and about 2501 bf.
 33. Agranule coated waterproof membrane, comprising: a non-woven fiberglassreinforcement layer; a plastic waterproof membrane layer on a first sideof the non-woven fiberglass fiber reinforcement layer; an asphaltcoating at least partially penetrating the reinforcement material on asecond side of the reinforcement material; and a layer of roofinggranules adhered to the asphalt coating.
 34. The roofing membraneaccording to claim 33, wherein the waterproof membrane layer is formedsubstantially from at least one of: ketone ethylene ester (KEE) resin,polyvinyl chloride (PVC), ethylene propylene diene monomer rubber(EPDM), and thermoplastic polyolefin (TPO).
 35. The roofing membraneaccording to claim 33, wherein the waterproof membrane layer is formedsubstantially from a blend of ketone ethylene ester and polyvinylchloride.
 36. The roofing membrane according to claim 33, wherein theasphalt coating is a polymer modified asphalt.
 37. The roofing membraneaccording to claim 36, wherein the polymer modified asphalt includes oneof styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS),styrene-butadiene (SB), and blends thereof.
 38. The roofing membraneaccording to claim 37, wherein the polymer modified asphalt furthercomprises at least one of a thermoplastic polymer and a thermoplasticpolyolefin.
 39. The roofing membrane according to claim 38, wherein thepolymer modified asphalt further comprises at least one of polyethylene,polypropylene, an ethylene-propylene copolymer, limestone, dolomite,talc, recycled roofing material, tackifying resin, process oil, and wax.40. The roofing membrane according to claim 33, wherein the roofingmembrane has a puncture resistance of 1751 bf or greater.
 41. Theroofing membrane according to claim 33, wherein the roofing membrane hasa puncture resistance between about 1751 bf and about 2501 bf.